NITROGEN-SULPHURIC FERTILIZERS BASED ON AMMONIUM NITRATE MELT AND PHOSPHOGYPSUM
Abstract
To obtain samples of nitrogen-sulphur fertilizers, the mass ratio of AS : FG was varied from 100 : 0.5 to 100 : 20. It was shown that the crystallization temperature of the nitrate melt decreases from 165 to 152°C. In the products, an increase in the water-soluble form of calcium from 0.06 to 2.86% indicates the reaction of ammonium nitrate with calcium sulfate dehydrate to form calcium nitrate and ammonium sulfate. At the studied ratios of AS : FG = 100 : (0.5 ÷ 20), the strength of the product granules increases from 4.09 to 7.67 MPa. At the same time, the caking of the product decreases from the initial 5.62 kg / cm2 to 1.83 kg / cm2 in the product, almost 3.1 times. Granules of gypsum-containing AS dissolve in water much more slowly than pure AS. Phosphogypsum in the composition of saltpeter promotes its conversion, and with an increase for additive, it increases.
About the Authors
List of references
Dobrovolskiy О.А., Lapidus А.S., Polyakov N.N. Quality of nitrogen fertilizers // Industry on mineral fertilizer production. Series. Nitrogen industry. – NIITEHIM. 1989. 56 p.
Оlevskiy V.М. Ammonium nitrate technology. Мoscow. Chemistry. 1978. 312 p.
Patent. USSR No 1502550. Cl. С05С 1/02. Method of reducing of ammonium nitrate packing / N.I.Orlov, V.M.Olevskiy, N.Е.Javaronkova, N.N.Polyakov, L.V.Кuznetsovа, E.Е.Аgafonova, А.F.Ilchenko, М.I.Кucha, V.К.Lyuskin. - B.I. 1989. No 31.
Levin B.V., Sokolov А.N. Issue and technical solution in complex fertilixer production based on ammonium nitrate // World of sulphur, N, P and К. – 2004. No 2. PP. 13-21.
Jmay L., Khristianova Е. Ammonium nitrate in Russia and the wide world. Modern condition and prospect // World of sulphur, N, P and К. – 2004. No 2. PP. 8-12.
Rasulov, O.X., Mamataliyev, A.A., Rasulova, D., Temirov, U., Namazov Sh.S. Physico-chemical properties lime-ammonium nitrate based on chalk, nitrate and ammonium sulphate // E3S Web of Conferences, 2021, 264, 04012.
Postnikov А.V. Production and application of calcium ammonium nitrate // Chemicalization of agriculture. – 1990. No 9. PP. 68-73.
Namazov Sh.S., Kushokov J.M., Mamataliyev A.A., Buriyev S.A., Nabiyev A.A. Phosphorus-containing lime-ammonium nitrate for agrochemical efficiency of crops // E3S Web of Conferences, 2023, 390, 05021.
Buriyev S.A., Namazov Sh.S., Mamataliyev A.A., Kushokov J., Quchqorov M., Shodikulov Z., Temirov U. Study on Non-caking Ammonium Nittle with the Additive of Arvaten Serpentinite // E3S Web of Conferences, 2024, 563, 02040.
Patent. No 2154620 Russia. Cl. С 05 С 1/02, С 05 D 1/00, С 05 G 1/06, С 05 D 5/00. Method of nitrogen-potassium fertilizer / V.F.Duhanin, А.I.Serebryakov – 20.08.2000. – B.I. – No 23.
Ilin V.А. Development of complex nitrogen-phosphoric fertilizer technology based on ammonium nitrate melt: PhD thesis in technique sciences, Ivanov State chemical engineering university, Ivanova. – 2006. – 17 p.
Ilin V.А., Rustambekov М.К., Акаеv О.P., Nenaydenko G.N. Investigation of complex nitrogen-phosphate fertilizer thermal stability // Issues on stabilization of fertility and yield in Vernevoje. – Мoscow. VNIIA. 2006. PP. 128-136.
Patent No 04527 РУз. Cl. 8С05G 1/00, С05В 7/00.С05С 1/00. Method of nitrogen-phosphate fertilizer / Sh.S.Namazov, B.B.Botirov, V.V.Pak, Sh.I.Salihov, А.М.Reymov, R.Yakubov, B.М.Beglov, R.К.Кurbaniyazov, N.N.Pirmanov, B.S.Zakirov. – 31.07.2012. –No 7.
Namazov Sh.S., Turdialiev U.М., Ortikova S.S., Reymov А.М., Beglov B.М. Preparation of thermostable ammonium nitrate based on its melt and bentonite from Uzbekistan // Chemical industry. – Saint-Petersburg. – 2016. No 1. – С.1-14.
Ibatov F.A., Namazov Sh.S., Mamataliyev A.A., Temirov U. Complex Nitrogen-phosphorus-sulfur-containing Fertilizers Based on Ammonia Salt, Phosphate Rock and Phosphogypsum // E3S Web of Conferences, 2024, 563, 03091.
Bozorov I.I, Iskandarova M.I, Mamataliyev A.A, Usanbayev N., Temirov U. Nitrogen-Sulfur-Containing Fertilizers Based on Melt Ammonium Nitrate and Natural Gypsum // AIP Conference Proceedings, 2022, 2432, 050062.
Methods of phosphate raw materials, phosphoric and complex fertilizers, feed phosphate analysis / М.М.Vinnik, L.N.Erbanova, P.М.Zaytsev and others. – Мoscow. Chemistry. 1975. 218 p.
Olevskiy V.М., Polyakov N.N. Results of industrial tests of ammonium nitrate on packing and friability // Abstract collection “Nitrogen industry”. // Мoscow. NIITEHIM. 1974. PP. 6-8.
Fridman S.D., Skum L.S. Solubility of potassium chloride in nitroammophos // Chemical industry. 1971. No 1. PP. 44-47.
Milashenko N.Z. Ammonium sulfate – perspective form of nitrogen fertilizer // Agrichemical bulletin. 2004. No 2. PP. 3.
How to Cite
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.