NONLINEAR OPTICAL (NLO) MATERIALS: SYNTHESIS, CRYSTAL STRUCTURE AND CHARACTERIZATION OF A NEW ORGANIC–INORGANIC HYBRID MATERIAL 4-(2-AMMONIOETHYL)MORPHOLIN-4-IUM HEXACHLOROSTANNATE(IV).
Abstract
4-(2-ammonioethyl)morpholin-4-ium hexachlorostannate(IV) formed a nonlinear optical material. The molecula obtained nonlinear optical material(NLO)=(2a4mh)2SnCl6·4-(2-ammonioethyl)morpholin-4-ium hexachlorostannate(IV). In all the crystal structures presented, cations and anions are arranged alternatively to form chain and ring hydrogen-bonding patterns consisting of weak unconventional N−H•••Cl hydrogen bonds. The compound was first analyzed using single-crystal X-ray diffraction to determine its crystal structure. Subsequently, FTIR (Fourier-transform infrared spectroscopy) and UV-visible absorption spectroscopy studies were conducted to provide insights into the compound's chemical composition and electronic transitions. Nonlinear optical materials were studied by Hirshfield surface analysis and crystal void parts and Elemental analysis.
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