NONLINEAR OPTICAL (NLO) MATERIALS: BIS(2-METHYL-4-NITROANILINIUM) HEXACHLORO-TIN(IV) MONOHYDRATE. QUANTUM CHEMICAL CALCULATIONS. SYNTHESIS, CRYSTAL STRUCTURE, HIRSHFELD SURFACE ANALYSIS, CRYSTAL VOIDS.
Referat
2-Methyl-4-nitroaniline (2m4na) and Tin(IV) chloride formed a nonlinear optical material. The molecula obtained nonlinear optical material(NLO)=(2m4na)2SnCl6·H2O-bis(2-Methyl-4-nitroanilinium)hexachloro-Tin(IV) monohydrate.In all the crystal structures presented, cations and anions are arranged alternatively to form chain and ring hydrogen-bonding patterns consisting of weak unconventional N−H•••Cl hydrogen bonds. The compound was first analyzed using single-crystal X-ray diffraction to determine its crystal structure. Subsequently, FTIR (Fourier-transform infrared spectroscopy) and UV-visible absorption spectroscopy studies were conducted to provide insights into the compound's chemical composition and electronic transitions. Nonlinear optical materials were studied by Hirshfield surface analysis and crystal void parts.
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